Hah, yeah, there are rules. I don't know how strict the judges are, but almost all winning entries across all their events so far have been superhero action outfits. I think only
the Fantastic Four winner seems to be the exception with the t-shirt and cargo pants ensemble (and even then, the judges' comments indicate that they viewed the outfits as superhero uniforms).
High fashion popstar designs might go over well with characters that are known to be performers (Dazzler, Lila Cheney, Zatanna, etc). Non-combat garb does well on that site for their non-events (like the civilian-wear section,
Off-Duty). If you really want to break from continuity, they also have
a section that dresses up characters in a new context.