maybe not entirely impossible, but at least very uncomfortable.
i.imgur.com/BkGFhsj.jpgfor the character to bend her left leg like that, the hip would have to be raised accordingly. the leg was drawn in profile, making the pose look slightly awkward.
also, the space between the overlapping left leg and right leg under it is shaded too darkly, creating an illusion of floating, which also helped me notice the leg. i would suggest more bounce-light, such as below.
i.imgur.com/FGxjjQE.jpg